Shake-up processes following K-shell photoionization in the Boron isoelectronic sequence

نویسندگان

  • S. Stoica
  • D. Petrini
چکیده

The direct and conjugate shake-up cross sections for the 2p → 3p, 3s and 2s → 2p, 3s transitions are calculated for CII, NIII, OIV, FV and NeVI in a close-coupling approximation using the R-matrix method. We find that the total shake-up cross section relative to that for single photoionization decreases with increasing Z. The decrease is about a factor 10 when going from BI to NeVI. When the full shake-up regime is reached, i.e. for about twice the 1s threshold energy, the cross section ratio ranges from about 15% for CII to about 3.5% for NeVI, of the single 1s inner-shell photoionization cross section. The 2s → 3s transition gives the dominant contribution for all ions. The 2p → 3p and 2s → 2p excitation contributions are broadly comparable in this energy range, while the 2p → 3s transition is negligible. Our results suggest that the importance of shake off excitation is significant for low Z ions.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

K-photoionisation of atomic carbon: shake up processes

We evaluate the shake up process in the K– photoionisation of atomic carbon, i.e. the 2s → 2p and 3s, and 2p → 3p shake up excitations, within the photon energy range 25 to 45 Ry. As in the atomic boron case, the 2s → 3s excitation is still relatively strong and due to configuration interaction effects dominates the 2p subshell excitation to 3p. The conjugate shake up 2s → 2p is 3% near 45 Ry, ...

متن کامل

Shake-up and shake-off excitations with associated electron losses in X-ray studies of proteins.

Photoionization of an atom by X-rays usually removes an inner shell electron from the atom, leaving behind a perturbed "hollow ion" whose relaxation may take different routes. In light elements, emission of an Auger electron is common. However, the energy and the total number of electrons released from the atom may be modulated by shake-up and shake-off effects. When the inner shell electron le...

متن کامل

Double K -shell photoionization and hypersatellite x-ray transitions of 12 Z 23 atoms

Single-photon double K-shell ionization of low-Z neutral atoms in the range 12 Z 23 is investigated. The experimental method was based on measurements of the high-resolution Kα hypersatellite x-ray spectra following the radiative decay of the K-shell double-vacancy states excited by monochromatic synchrotron radiation. The photon energy dependence of the double K-shell ionization was measured o...

متن کامل

Double K-shell photoionization of low-Z atoms and He-like ions

We report on the investigation of the photon energy dependence of double 1s photoionization of light atoms and compare the cross sections for hollow atom and He-like ion production. Measurements of the Kα hypersatellite x-ray spectra of Mg, Al, and Si were carried out using the Fribourg high-resolution x-ray spectrometer installed at the ID21 and ID26 beam lines at the ESRF. The double-to-singl...

متن کامل

Ab initio determination of satellite intensities in transition-metal photoemission spectroscopy using a multiconfiguration framework

Following atomic photoionization, the abrupt change in potential can lead to secondary ionization of an outer-shell electron in a phenomenon known as shake-off, a process which gives rise to the asymmetric Kα profile and satellite lines. Investigation of chemical effects and relativistic quantum mechanics requires a theoretical determination of these satellite intensities; however, existing the...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 1998